This is something i have been looking into aswell. Im sure you could get a better camshaft for that head and if you can get stiffer springs for that head then i would, i understand the XSI head already has a decent cam from standard but im sure you would benefit from something a bit more lairy.
Also i would'nt go for larger valves as this can mess up the flow or VE, big valve conversions are more for turbo charged engines were the oe valves are actually bottle-necking the airflow into the cylinder.
And get the head professionally ported and polished and flow bench/ tested if your going to the effort of tuning the head